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The molecular structures of some intermediate and end products of the fc.rmose reaction are determined by means of coupled gas chromatography/mass spectrometry and by PFT 13C NMR spectroscopy. It is shown that glycolaldehyde, glyceraldehyde and dihydroxiacdone, which are intermediate products, are not single compounds but mixtures of monomers: hydroxicarbonyl compounds, epoxides, hydrates and dimers: half acetalrand full acetals. The structure of KUSIN's prod\lct, which is a key substance in LANGENBECK's theory ofautocatalysis is confirmed to be hydroximethylbenzoine. Only a minor tendency of a fission into benzoine and "active formaldehyde" but decomposition of the catalyst by fission into benzoic acid is observed. The structure of UTKIN's product is confirmed to be a branched chain ketohexose caII~d dendroketose. Using heterogenous call;iumhydroxide as a catalyst UTKIN's yields of dendroketose are doubled.read more
G HARSCH ,
- 15 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 95
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The complexation of Bi{III) with chloride ion has been studied in non-aqueous medium. The state and behaviour of BielS and its higher complexes have been examined in organic solvents. This attempt is merely an addition to the study of Bi{III) complexes with potassium diphenyldiselenophosphate where Bi{I1I) forms complexes of definate (l:S) composition.read more
A RAFEE ,N T YATSIMIRSKAYA ,
- 15 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 105
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Lactarn acetals undergo facile e1ectrophilicsubstitution at II positioH with araldehydes to fonn benzhydrols. Both threo and erythro products are formed, their proportion depending upon the aldehyde; the products unfacile dehydration to form (E)-ll-benzylidene derivatives. Ibc threo oamino benzhydrols obtained as the exclusive products by reaction of lactarn acetals with amin aldehyde undergo instantaneous cyclisation to give a novel one pot synthesis of l-substituted azacycloalkano (2, 3-b )quinolines.read more
P C JAIN ,J SINGH ,V VIRMANI ,N ANAND ,
- 16 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 109
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ApuIse-radiolytic study shows that the anion of biphenyl decayed in liquid methyla~ mine via a first order process. The absorptions at 410 and 640 nm both decyed With the same rate constant. k is (2.4 :t 0.3) x 105 i1 in the concentration range 1.16 x 10- •.. 5 x 10-2 mol dm-3 of biphenyl. \iowever, in a 5 x 10-4 mol dm-3 solution of biphenyl 1 k is (1.1 :t 0.06) x 105 i1• The anion of pyrene showed an absorption spectrum With a maximum at 490 nm. It decayed by a second order process haviJ}g 2k:: (3.5 :t 0.4) x 105 e490 dm3 mor1 i1• When a solution ofpyrene containing 10-3 mol dm-3 methylamine hydrochloride was irradiated, the order of the decay remained unchanged, but 2k was reduced to (1.3 :t 0.2) x 105 e490 dm3 mol:1 i1•read more
M A SAMI ,
- 16 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 117
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Thin film of copper metal was vacuum deposited on KRS-5 internal reflection prism.Infrared Internal Reflection Spectrometry was employed to observe the chemical reaction taking place at the resulting metal surface with IO-6M glycine solutio~ of 8.2 pH. The investig-dtion shows that the formation of Cu(l) glycinate chelate was formed at the surface of a film of cuprous oxide.read more
J S MATTSON ,I A KHAN ,
- 17 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 121
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A new· method is described for the synthesis of b-carbolines from indolic imides by reaction of the intermediate vilsmeier complexes with zinc. read more
A U RAHMAN ,N WAHEED ,
- 17 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 125
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Synthesis of 6,9-Diazadibenzo [c,g]phenanthrene and 7 ,13-Diazadibenzo [c)i] phenanthrene through Double Benzyne Cyclisation1read more
P S PAHWA ,Y P GUPTA ,V JAIN ,P SINGH ,S V KESSAR ,
- 17 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 129
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Photochemical transformation are outlined with novel stereochemical or other mechanistic features leading to the synthesis of 4b-19-methyl-imino-50a-cholestane.read more
A M FARID ,J McKENNA ,J M McKENNA ,
- 17 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 131
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Synthesis of N-(methyl-6-deoxy-(beta)-D-glucopyranos-6-ide) saccharinread more
C K LEE ,
- 17 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 133
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A partial. structure for juliflorine, an alkaloid from Prosopis juliflora, DC has been proposed.read more
V U AHMAD ,Z G MOHAMMAD ,
- 17 Aug 2011
- Volume Detail: VOLUME 1, NO2, DEC 1979
- Pages: 137
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